Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst
Caterina S. Aricó and Liam R. Cox*
*School of Chemistry, The University of Birmingham, Edgbaston, Birmingham,
UK B15 2TT. Email: l.r.cox
bham.ac.uk
C. S. Arico, L. R. Cox, Org. Biomol. Chem., 2004, 2, 2558-2562.
DOI: 10.39/b409832c
Abstract
Grubbs' first-generation Ru metathesis complex catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.
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Key Words
Vinylsilanes, Vinylsiloxanes, Alkynes
ID: J52-Y2004-750
