Preparation of Silyl Enol Ethers Using (Bistrimethylsilyl)acetamide in Ionic Liquids
Michael Smietana and Charles Mioskowski*
*Laboratoire de Synthèse Bio-organique, CNRS and Université Louis Pasteur, Faculté de Pharmacie, 74 Route du Rhin, 67401 Illkirch, France. Email: mioskowaspirine.u-strasbg.fr
M. Smietana, C. Mioskowski, Org. Lett., 2001, 3, 1037-1039.
DOI: 10.1021/ol015602h
Abstract
Various ionic liquids have been tested for the preparation of silyl enol ethers from aldehydes and ketones with (bistrimethylsilyl)acetamide (BSA). Yields have been strongly influenced by the nature of the cation of the ionic liquid.
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Key Words
Silyl enol ethers, Ionic Liquids
ID: J54-Y2001-490