Hydroamination/Hydrosilylation Sequence Catalyzed by Titanium Complexes
Andreas Heutling, Frauke Pohlki, Igor Bytschkov, Sven Doye*
*Institut für Reine und Angewandte Chemie, Universität
Oldenburg, Carl-von-Ossietzky-Strasse 9-11, 26111 Oldenburg, Germany, Email:
doye
uni-oldenburg.de
A. Heutling, F. Pohlki, I. Bytschkov, S. Doye, Angew. Chem. Int. Ed., 2005, 44, 2951-2954.
DOI: 10.1002/anie.200462250
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Abstract
The sequential combination of Ti-catalyzed hydroamination of alkynes followed by the Ti-catalyzed hydrosilylation of the intermediate imines is an efficient one-pot process for the conversion of alkynes and primary amines into secondary amines.
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Key Words
alkynes, arylamines, hydroamination, hydrosilylation, titanium, phenylsilane
ID: J06-Y2005-510
