Using Geminal Dicationic Ionic Liquids as Solvents for High-Temperature Organic Reactions
Xinxin Han and Daniel W. Armstrong*
*Department of Chemistry, Iowa State University, Ames, Iowa 50011, Email: sec4dwaiastate.edu
X. Han, D. W. Armstrong, Org. Lett., 2005, 7, 4205-4208.
DOI: 10.1021/ol051637w (free Supporting Information)
The utility of dicationic ionic liquids for high-temperature organic reactions such as Claisen rearrangement, isomerizations, and the Diels-Alder reaction was demonstrated. Advantages of these solvents are high thermal stability and recyclability.
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