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A remarkable solvent effect toward the Pd/C-catalyzed cleavage of silyl ethers

Hironao Sajiki*, Takashi Ikawa, Kazuyuki Hattori and Kosaku Hirota

*Laboratory of Medicinal Chemistry, Gifu Pharmaceutical University, 5-6-1 Mitahora-higashi, Gifu 502-8585, Japan, Email:

H. Sajiki, T. Ikawa, K. Hattori, K. Hirota, Chem. Commun., 2003, 654-655.

DOI: 10.39/b211313a


Selective hydrogenation conditions of olefin, benzyl ether and acetylene functionalities in the presence of TBDMS or TES ether have been developed.

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Key Words

TBDMS Ethers, Hydrogenation, Hydrogen

ID: JXX-Y2003-1210