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Bis(methanesulfonyl) peroxide


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The use of bis(methanesulfonyl) peroxide as an oxidant enables a selective synthesis of benzylic alcohols without further oxidation of alcohols to ketones. A proton-coupled electron transfer mechanism (PCET) may account for the difference in reactivity.
L. Tanwar, J. Börgel, T. Ritter, J. Am. Chem. Soc., 2019, 141, 17983-17988.