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Iodine pentoxide

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A facile I2O5-mediated direct oxidative coupling of aromatic alkenes with thiols provides various (E)-vinyl sulfones from readily available starting materials with excellent regioselectivity under metal-free conditions.
L. Wang, H. Yue, D. Yang, H. Cui, M. Zhu, J. Wang, W. Wei, H. Wang, J. Org. Chem., 2017, 82, 6857-6864.