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Methanol


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An anionic iridium complex [Cp*Ir(2,2'-bpyO)(OH)][Na] is a general and highly efficient catalyst for transfer hydrogenation of ketones and imines with methanol as hydrogen source under base-free conditions. Nitro, cyano, and ester groups were tolerated under the reaction conditions.
R. Wang, X. Han, J. Xu, P. Liu, F. Li, J. Org. Chem., 2020, 85, 2242-2249.


An anionic iridium complex [Cp*Ir(2,2'-bpyO)(OH)][Na] is a general and highly efficient catalyst for transfer hydrogenation of ketones and imines with methanol as hydrogen source under base-free conditions. Nitro, cyano, and ester groups were tolerated under the reaction conditions.
R. Wang, X. Han, J. Xu, P. Liu, F. Li, J. Org. Chem., 2020, 85, 2242-2249.


An air and moisture stable manganese pincer complex catalyzes the semireduction of various alkynes to the corresponding (Z)-olefins in high yields. The reaction is stereo- and chemoselective and scalable.
J. Sklyaruk, V. Zubar, J. C. Borghs, M. Rueping, Org. Lett., 2020, 22, 6067-6071.