Triethylphosphite
See also: trimethylphosphite
Recent Literature
An experimentally simple, fast, mild, and scalable transition-metal-free
cross-coupling between boronic acids and nitrosoarenes enables the synthesis of
di(hetero)arylamines. The procedure tolerates a wide range of functional groups,
including carbonyls, nitro, halogens, free OH and NH groups, and also permits
the synthesis of sterically hindered compounds.
S. Roscales, A. G. Csák˙, Org. Lett.,
2018, 20, 1667-1671.
A new, mild protocol for deoxygenation of various phosphine
oxides with retention of configuration is described. Mechanistic studies
regarding the oxygen transfer between the starting phosphine
oxide and triphenylphosphine are also presented.
H.-C. Wu, J.-Q. Yu, J. B. Spencer, Org. Lett.,
2004, 6, 4675-4678.
Trialkyl phosphites mediate a convenient, efficient, and inexpensive
deoxygenation of 1,2,3-triazine 1-oxide for the synthesis of 1,2,3-triazine
derivatives in high yield. Triethyl phosphite is more reactive than trimethyl
phosphite, and both phosphites form their corresponding phosphates in these
reactions.
G. Rivera, L. De Angelis, A. Al-Sayyed, S. Biswas, H. Arman, M. P. Doyle, Org. Lett.,
2022, 24, 6543-6547.
