Further Information
Literature
Related Reactions
Eglinton Reaction
Glaser Coupling
Synthesis of 1,3-Diynes
Cadiot-Chodkiewicz Coupling
The copper(I)-catalyzed coupling of a terminal alkyne and an alkynyl halide offers access to unsymmetrical bisacetylenes.
Mechanism of the Cadiot-Chodkiewicz Coupling
Recent Literature
Copper(I) Iodide Catalyzed Cross-Coupling Reaction of Terminal Alkynes with
1-Bromoalkynes: A Simple Synthesis of Unsymmetrical Buta-1,3-diynes
S. Wang, L. Yu, P. Li, L. Meng, L. Wang, Synthesis, 2011,
1541-1546.
Synthesis of 1,3-Diynes via Cadiot-Chodkiewicz Coupling of Volatile, in Situ
Generated Bromoalkynes
P. C. Knutson, H. E. Fredericks, E. M. Ferreira, Org. Lett.,
2018, 20, 6845-6849.
Bulky Trialkylsilyl Acetylenes in the Cadiot-Chodkiewicz Cross-Coupling
Reaction
J. P. Marino, H. N. Nguyen, J. Org. Chem., 2002, 67, 6841-6844.
End-Cap Stabilized Oligoynes: Model Compounds for the Linear sp Carbon
Allotrope Carbyne
T. Gibtner, F. Hampel, J.-P.Gisselbrecht, A. Hirsch, Chem. Eur. J.,
2002, 68, 408-432.