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Search results for: *tamao* oxidation
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... Organic Chemistry Portal K. Tamao, in Comprehensive Organic ... tamao-k.shtm ...
... , Alcohols , Phenols , Tamao-Fleming Oxidation ID: J54-Y2003-1270 ... Organic Chemistry Portal Oxidation of Carbon-Silicon Bonds: The ... exposure to aqueous fluoride and peroxide. These tetraalkylsilanes offer ...
... fluorosilane, set for the Tamao oxidation that revealed the ... stage for intramolecular opening and oxidation to give 9. ... to the alcohol 8. Epoxidation occurred from the more ...
... examples Key Words Hydrosilylation , Tamao-Fleming Oxidation , 1, ... chiral monophosphine-palladium complex and an oxidation with hydrogen peroxide gave ... ,2-diols of high enantiomeric purity in high yields. ...
... (Cl)] as catalyst. Fleming-Tamao oxidation of the resulting 6-membered oxasilolanes provides ... ,4-diols. see article for more examples reaction pathway Key Words Hydroxylation , Fleming-Tamao ...
... substituted aromatic alkenes, giving access after Tamao oxidation to almost optically pure benzylic alcohols ... high yields. see article for more examples Key Words Benzylsilanes , Tamao Oxidation ID ...
... a mild and practical alternative to the Tamao-Fleming oxidation of vinylsilanes and the Arndt-Eistert homologation ... range of functionalized alkenes. In situ oxidation of the resulting alkylradical intermediates, followed ...
... Words Conjugate Additions , Boronic Acids , Tamao Oxidation , ?-hydroxy ketones ID: J54-Y2005-1740 ... Carbon-Carbon Bond-Forming Enantioselective Synthesis of Chiral Organosilicon Compounds by Rhodium/Chiral Diene-Catalyzed Asymmetric 1 ...
... stereochemistry using mercuridesilylation, (a modified Tamao-Flemming oxidation ) . Also noteworthy in the ... 1 paper was the chain reduction of an aldehyde by formation of the corresponding silyl ...
