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Search results for: ireland-claisen rearrangement

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... the key quaternary stereocenter generated in a Ireland-Claisen rearrangement . The rearrangement precursor - an ... ester - is easily deconstructed into an alcohol partner stemming from D-ribose, and an ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn04/pinnatoxin-a-zakarian.shtm
... see article for more examples Key Words Ireland-Claisen Rearrangement , Silanes ID: J72-Y2002-860 ...
URL: https://www.organic-chemistry.org/abstracts/literature/706.shtm
... 5, 395. Key Words: IRELAND-CLAISEN REARRANGEMENT; OXY-COPE REARRANGEMENT; ALPHA-AMINO-ACIDS; ... [3 ,3 ] -sigmatropic rearrangments. S. M. Allin, ...
URL: https://www.organic-chemistry.org/abstracts/authors/allin-s-m.shtm
... ) to assemble this ring by the Ireland-Claisen rearrangement of the lactone 1. The ... configuration of the final product stemmed from the commercial enantiomerically-pure acetonide 4, that was ...
URL: https://www.organic-chemistry.org/Highlights/2013/04March.shtm
... conversion to the fully-substituted alkene 7. Ireland-Claisen rearrangement of the isobutyrate derived from 7 ... with substantial preference for the equatorial diastereomer 8. This was carried on to the ...
URL: https://www.organic-chemistry.org/Highlights/2015/02November.shtm
... 2013, 15, 4406. ) Ireland-Claisen rearrangement of the lactone 4 to give ... pyrrolidine 5 with high geometric control. This was readily converted to Limazepine E ( ...
URL: https://www.organic-chemistry.org/Highlights/2014/12May.shtm
... prepared in by a route involving an Ireland-Claisen rearrangement and a reductive 1,6-enyne ... 4 with singlet oxygen followed by Kornblum-DeLaMare rearrangement with DBU to afford ketone 5. ...
URL: https://www.organic-chemistry.org/Highlights/2014/21April.shtm
... 17433. ) high diastereoselectivity in the Ireland-Claisen rearrangement of 4 to 5. The ... 5 was the key intermediate for the synthesis of the tunicate alkaloid Lepadiformine (6 ...
URL: https://www.organic-chemistry.org/Highlights/2015/11May.shtm
... ; SELECTIVE 1,4-CHIRAL INDUCTION; IRELAND-CLAISEN REARRANGEMENT; INTERNAL ASYMMETRIC INDUCTION; DELTA-HYDROXY ... 2 ,3 ] -Wittig sigmatropic rearrangement. K. Mikami, T. ...
URL: https://www.organic-chemistry.org/abstracts/authors/mikami-k.shtm
... . On deprotonation followed by silylation, Ireland-Claisen rearrangement proceeded with high diastereocontrol. The ... 7 was carried on to ( -) -lepadiformine 8. Two recent syntheses ...
URL: https://www.organic-chemistry.org/Highlights/2007/08January.shtm
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