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Search results for: epoxidation

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... product silanes are easily oxidized to the corresponding alcohols. Another alternative to hydroboration is epoxidation followed by selective reduction of the more substituted end of the epoxide. Juan ...
URL: https://www.organic-chemistry.org/Highlights/2007/12March.shtm
... . 843. Key Words: FUNCTIONAL GROUPS/OXIDATION/ALKENES AND ALKYNES/EPOXIDATION/EPOXIDE HETRING/3(O) Oxaziridine rearrangements in asymmetric synthesis. ...
URL: https://www.organic-chemistry.org/abstracts/authors/aube-j.shtm
... Chem. Int. Ed. 2006, 45, 1429.) his enantioselective epoxidation protocol to arylidene cyclobutanes such as 1. The epoxide 2, formed in ...
URL: https://www.organic-chemistry.org/Highlights/2007/20August.shtm
... Winssinger of the Université Louis Pasteur in Strasbourg prepared the substrate 20 for Sharpless asymmetric epoxidation using the method that we introduced (J. Org. Chem. 2003 ...
URL: https://www.organic-chemistry.org/Highlights/2007/22January.shtm
... /APPENDAGES/ENANTIOGENIC REACTIONS/ORGANOMETALLICS/SYNTHESIS/TM CATALYSTS/REDUCTION SHARPLESS EPOXIDATION CYCLOPROPANATION DIELS-ALDER ALDOL HYDROGENATION CROSS COUPLING HYDROFORMYLATION/HETRING/3(O) ...
URL: https://www.organic-chemistry.org/abstracts/authors/brunner-h.shtm
... The alcohol so produced (not illustrated) was used to direct the diastereoselectivity of epoxidation, then removed, to give 13. Coupling with 14 then led to ...
URL: https://www.organic-chemistry.org/Highlights/2008/04August.shtm
... been developed for acyclic stereocontrol. Beginning with the allylic alcohol 4, Sharpless asymmetric epoxidation established the absolute configuration of 5. Following the Jung “non-aldol aldol” ...
URL: https://www.organic-chemistry.org/Highlights/2008/07January.shtm
... , 130, 6070.) a chiral primary amine salt that catalyzed the enantioselective epoxidation of cyclohexenone 1. Larger ring and alkyl-substituted enones are also epoxidized with high ...
URL: https://www.organic-chemistry.org/Highlights/2008/22December.shtm
... CHIRAL CENTERS/SINGLE ISOMERS E/UNSATURATED-ACIDS/1,1-DIPHENYLPHOSPHOLANIUM PERCHLORATE/STEREOSELECTIVE EPOXIDATION/NUCLEOPHILIC-ATTACK ...
URL: https://www.organic-chemistry.org/abstracts/authors/clayden-j.shtm
... of Delaware Reactions of Alkenes One of the most powerful of alkene transformations is enantioselective epoxidation. Tsutomu Katsuki of Kyushu University has developed (Angew. Chem. Int ...
URL: https://www.organic-chemistry.org/Highlights/2008/29September.shtm
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