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... Organic Chemistry Portal Guanidine Bases in Synthesis: Extending the Scope of the Corey-Chaykovsky Epoxidation David J. Phillips, Andrew E. Graham* *School of Chemistry ...
URL: https://www.organic-chemistry.org/abstracts/lit2/836.shtm
... rest of the synthesis was a whole lot more exciting, if based predominately on epoxidation/opening. However, it ' s quite the master class, so ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn02/intricatetraol-morimoto.shtm
... the reaction in trifluoroethanol. Many polyoxometalates have been developed that catalyze the hydrogen peroxide epoxidation of alkenes. Usually, these are simple electrophilic processes. Noritaka Mizuno of ...
URL: https://www.organic-chemistry.org/Highlights/2006/25September.shtm
... , one of which is allylic, so was a perfect candidate for a Sharpless epoxidation. The isoprene-type unit was deactivated by oxidation of the terminal methyl group to ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn05/dioxepandehydrothyrsiferol-jamison.shtm
... , 17. Key Words: SILYL ENOL ETHERS/OXIDATION-REDUCTION HYDRATION/COMPLEX CATALYZED EPOXIDATION/BAEYER-VILLIGER OXIDATION/SCHIFF-BASE COMPLEXES/ALPHA-HYDROXY KETONES/MOLECULAR-OXYGEN/ASYMMETRIC EPOXIDATION ...
URL: https://www.organic-chemistry.org/abstracts/authors/mukaiyama-t.shtm
... MOLECULAR-SIEVE CATALYSTS; TANTALUM HYDRIDE COMPLEX; X-RAY-ABSORPTION; MESOPOROUS SILICA; HETEROGENEOUS CATALYSTS; EPOXIDATION CATALYSTS; HYDROCARBON OXIDATION; AERIAL OXIDATION; ADIPIC ACID Molecular sieve catalysts for ...
URL: https://www.organic-chemistry.org/abstracts/authors/thomas-j-m.shtm
... Design of Sulfides with a Locked Conformation as Promoters of Catalytic and Asymmetric Sulfonium Ylide Epoxidation Marion Davoust, Jean-François Brière, Paul-Alain Jaffrès and Patrick Metzner* *Laboratoire ...
URL: https://www.organic-chemistry.org/abstracts/literature/883.shtm
... bromide, setting, after hydrolysis, the new secondary stereocenter of 9. Hydroxyl-directed epoxidation gave 10, which was rearranged with Ti(O-i-Pr) 4 to 11 ...
URL: https://www.organic-chemistry.org/Highlights/2005/02May.shtm
... achieved. Epoxy alkynes such as 1 can be prepared in high ee by Sharpless epoxidation. Norbert Krause of Dortmund University has shown (Angew. Chem. Int ...
URL: https://www.organic-chemistry.org/Highlights/2007/19November.shtm
... to become available, and still one of the most valuable, is Sharpless asymmetric epoxidation. Karl Anker Jørgensen of Aarhus University, Denmark, devised (J. ...
URL: https://www.organic-chemistry.org/Highlights/2007/26February.shtm
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