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Search results for: epoxidation

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... alkene geometry. Pd-mediated coupling then delivered 3. The preparation of 1 began with epoxidation of carvone followed by oxidative cleavage, to give the keto acid 11. ...
URL: https://www.organic-chemistry.org/Highlights/2016/04January.shtm
... Chem. 2015, 80, 3203.) an improved procedure for the iconic epoxidation of geraniol 1 to 2. John R. Falck of UT Southwestern Medical ...
URL: https://www.organic-chemistry.org/Highlights/2016/22February.shtm
... To establish the absolute configuration of 3, the authors took advantage of Sharpless asymmetric epoxidation. To this end, farnesyl acetate 7 was oxidized with SeO 2 to ...
URL: https://www.organic-chemistry.org/Highlights/2017/03April.shtm
... Engl., 1994, 33, 175. Key Words: Li Catalytic asymmetric epoxidation and aziridination mediated by sulfur ylides. Evolution of a project. V. ...
URL: https://www.organic-chemistry.org/abstracts/authors/aggarwal-v-k.shtm
... oxygen transfer from acyl and alkyl hydroperoxides to metal(III) porphyrins and the epoxidation of alkenes by the resultant hypervalent metal-oxo porphyrin products. T. C. ...
URL: https://www.organic-chemistry.org/abstracts/authors/bruice-t-c.shtm
... , doing a rather tasty Favorskii rearrrangement on the cyclohexanone (built itself from an epoxidation on carvone, and then opening with chloride). This also generated a ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn03/thapsigargin-ley.shtm
... Words: tetrabutylammonium peroxydisulfate/tetrahydrofuranylation/oxidation/formylation/iodination/deprotection/epoxidation/N-BUTYLAMMONIUM PEROXYDISULFATE/BIS(PYRIDINE)IODONIUM(I) TETRAFLUOROBORATE/ ...
URL: https://www.organic-chemistry.org/abstracts/authors/kim-y-h.shtm
... tax the group at all; first up was installation of the tertiary alcohol by epoxidation of the silyl enol ether. Desilylation gave them the desired hydroxyl group and ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn05/be-43472b-nicolaou.shtm
... Alkylzinc Reagents to Cyclic ?,?-Unsaturated Ketones and a Tandem Enantioselective Addition/Diastereoselective Epoxidation with Dioxygen S .-J. Jeon, P. J. Walsh, J ...
URL: https://www.organic-chemistry.org/abstracts/literature/287.shtm
... , and lactones such as 13. For more than two decades, Sharpless asymmetric epoxidation of allylic alcohols has been the workhorse for enantioselective synthesis. Karl Anker Jørgensen ...
URL: https://www.organic-chemistry.org/Highlights/2006/13February.shtm
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