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Search results for: stille coupling

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... toluene, giving a ?-ketoamide. A Stille reaction was then used for the coupling ... the acrylate unit, and was followed by a intramolecular (Lacey) Dieckmann cyclisation ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn04/aburatubolactam-a-phillips.shtm
... I was intrigued by was a modified Stille coupling of cortistatinone (the core of ... natural product) with an aryl stannane. Baran did this by first forming the ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn04/cortistatin-a-baran.shtm
... C-glycosides/annulation/Heck reaction/Stille reaction palladium-mediated cyclization/enantiopure tricyclic compounds ... cross-coupling reactions/c-glycoside synthesis/catalyzed cyclization/furanoid glycals/enol ethers/ ...
URL: https://www.organic-chemistry.org/abstracts/authors/zamojski-a.shtm
... . The final cyclisation goes via a Stille coupling, using the trans-vinyl stannane and ... cis-vinyl iodide. However, more interesting to me was the condensation approach for creation ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn01/sarain-a-overman.shtm
... this the intermediate was built by a Stille-like biaryl coupling, and Henry reaction/ ... to install the pendant amine. Treatment of the phenol with Salcomine (a reversible ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn04/exiguamine-a-b-trauner-andersen.shtm
... enol triflate, which reacted in a Stille coupling with tri-n-butylstannylmethanol to the hydroxymethyl derivative ... Deprotection of the Boc group and we are done! ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn04/minfiensine-qin.shtm
... m-hydroxy-phenol delivering the electrophilic component for a Stille reaction. Coupling to an allyl silane ... and elimination of a mesyl group then finished the cyclisation substrate, which was treated ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn02/11-o-debenzoyltashironin-danishefsky.shtm
... stop reaction of the triene before the Stille coupling. Great work! ... Total Synthesis of Apoptolidinone A by Koert ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn02/apoptolidinone-a-koert.shtm
... homologation then gave the precursor 15 for Stille coupling to close the last ring. ... of the hemiaminal, oxidation with bicarbonate-buffered Dess-Martin reagent to the aldehyde (zwitterionic! ...
URL: https://www.organic-chemistry.org/Highlights/2007/04June.shtm
... As anticipated, the polyene prepared by Stille coupling of the iodide 25 with the ... 26 underwent 8 ? cyclization to 27, that then spontaneously underwent 8 ? cyclization ...
URL: https://www.organic-chemistry.org/Highlights/2008/22December.shtm
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