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Search results for: cope rearrangement
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... . Sequential imine formation, aza- Cope rearrangement , and hydrolysis led to 1 ... 94% de. One could envision reduction of the lactam carbonyl of 1 to ...
... . This convenient method offers broad substrate scope and good functional group tolerance. see ... The reaction may proceed via consecutive Baeyer-Villiger-type rearrangement followed by an intermolecular cyclization. This ...
... to give, after methyl coupling and oxy-Cope rearrangement , a ketone that condensed with ... vinyl ketone 27 to give 31. Bor-Cherng Hong of the National Chung Cheng University ...
... the enantiomercially-pure 7 on, by Pd-catalyzed Cope rearrangement , to 8 and so to ... -) -Kainic Acid (9 ) . M. Lluïsa Bennasar of the University ...
... STEREOCONTROLLED TOTAL SYNTHESIS/CHROMIUM-REFORMATSKY REACTION/SILYLOXY-COPE REARRANGEMENT/EFFICIENT TOTAL SYNTHESIS/LOW-VALENT ... /NEOCARZINOSTATIN CHROMOPHORE ANALOGS/ENANTIOSELECTIVE TOTAL SYNTHESIS/CONTAINING NATURAL-PRODUCTS Venturing into catalysis based ...
... L. Kristensen of the University of Copenhagen set the absolute configuration of 4 by ... . Diastereoselective N-alkylation with 6 followed by rearrangement led to 7, establishing the key ...
... et al. from Glaxo-Smith-Kline investigated in-depth scope and limitations of this imidazole synthesis ( ... bond, a base-induced cyclisation and proton rearrangement towards an imidazoline, which upon loss ...
... + 3] cycloaddition (aza- Cope rearrangement ) to give a ten-membered ring ... . This sequence was followed by a Mannich reaction. Only two further steps were ...
... Cyclopropenone Ketals, and Related Systems: Scope and Applications. D. L. ... AGENT/INHIBITORS PDE-I/BENZYLIC HYDROPEROXIDE REARRANGEMENT/ENHANCED FUNCTIONAL ANALOGS/MINOR-GROOVE BINDING ...
... mild reaction conditions and a broad substrate scope. see article for more examples Decarbonylative ... promotion of Ag2O and a subsequent DMAP-catalyzed rearrangement. This protocol offers mild reaction conditions ...
