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Search results for: epoxidation
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... about a conjugate addition to the unsaturated epoxide; work by James Marshall suggested that ... Ferrier rearrangement . The olefin was then epoxidised with mCPBA . This epoxy lactol was ...
... Selective Reaction of CO2 with Enantiopure Amino Epoxides under Mild Reaction Conditions. Synthesis and ... more reactions Abstract The reaction of chiral 1-aminoalkylepoxides with CO2, generated from acidic treatment ...
... /jo060512h) . The reaction of epoxides 1 with a variety of substituted primary ... proceeds via an epoxide-opening (A )/ cylization (via SNAr, B) ...
... : 10.1021/acs.orglett.6b02405) the bis epoxide 8 with the carbene derived from 9 ... give the monoepoxide 10. Several methods for the selective reduction of halides have been ...
... absolute configuration being set by Sharpless asymmetric epoxidation . Subsequent to the alkylation of 11 ... the nucleophile, opening of racemic isoprene monoepoxide 5 using the Trost chiral Pd catalyst ...
... of 8, prepared by Sharpless asymmetric epoxidation followed by Sharpless asymmetric dihydroxylation , also ... ) the preparation and reductive cyclization of polyepoxides such as 22. Hiroki Oguri and ...
... /acs.joc.5b01472) that opening of the epoxide 22, readily prepared with in situ ... C5CC05736A) Payne rearrangement of the symmetrical bis-epoxide derived from 1 ( SAE ) to ...
... /2 ,3-EPOXY AMINES/ASYMMETRIC EPOXIDATION/ALPHA-ACETOXYSULFIDES/PHENYLTHIO MIGRATION/NUCLEOPHILIC-ATTACK ... Lewis acid induced rearrangement of 1-hetero-2,3-epoxides. Synthesis, reactivity and synthetic applications ...
... led to the diene 16. Diastereoselective epoxidation completed the synthesis of gedunin (3 ... with furfuryl alcohol 4 and racemic isoprene monoepoxide 5. Following the Krische protocol, ...
... 4-SUBSTITUTED CYCLOHEXANONES/RELATIVE CONFIGURATION/SYMMETRICAL EPOXIDES ...