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... followed by MOM protection gave 15. Nozaki-Hiyama-Kishi (NHK) cyclization of the derived ... to give, after reduction and cyanide coupling, the nitrile 11. Release of ...
... in further synthetic applications, such as Hiyama Denmark coupling and epoxidation. This work ... a robust and reliable strategy for anti-silylative functionalizations, expanding the toolkit for the synthesis ...
... . This necessitates eventual deprotection. Shigeru Nishiyama of Keio University, Yokohama has shown ... addition to being good leaving groups for coupling reactions, sulfonates, e.g. a ...
... carbonyl species then allowed regioselective and diastereoselective Nozaki-Hiyama-Kishi (NHK) cyclisation. Opening of ... them to proceed. Performing a Negishi coupling with a TMS-protected acetylene then presented another ...
... them a synthetic handle, allowing a Hiyama-type coupling to the aryl iodide. With ... inplace, they removed the pivolyl protecting group, and performed a tandem epoxidation/ ...
... , 129, 2752-2753. Key Words Nozaki-Hiyama Coupling , Homoallylic Alcohols ID: J54-Y2005-490 ... Stereochemical Diversity in Chiral Ligand Design: Discovery and Optimization of Catalysts for the Enantioselective ...
... 1837-1839. Key Words Homoallylic Alcohols , Nozaki-Hiyama Coupling ID: J48-Y2007-0780 ...
... Key Words ?-hydroxy aldehydes , allylation , Nozaki-Hiyama Coupling , manganese ID: J48-Y2010-1580 ...
... article for more examples ligand Key Words Nozaki-Hiyama coupling , lactones ID: J54-Y2015 ...