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Search results for: ireland-claisen rearrangement
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... prepared in by a route involving an Ireland-Claisen rearrangement and a reductive 1,6-enyne ... 4 with singlet oxygen followed by Kornblum-DeLaMare rearrangement with DBU to afford ketone 5. ...
... of Chugai Pharmaceutical Co. optimized the Ireland-Claisen rearrangement of 18 to 19 (Org ... reduction of 16, leading, after rearrangement of the intermediate allyl diazene, to ...
... ; SELECTIVE 1,4-CHIRAL INDUCTION; IRELAND-CLAISEN REARRANGEMENT; INTERNAL ASYMMETRIC INDUCTION; DELTA-HYDROXY ... 2 ,3 ] -Wittig sigmatropic rearrangement. K. Mikami, T. ...
... . On deprotonation followed by silylation, Ireland-Claisen rearrangement proceeded with high diastereocontrol. The ... 7 was carried on to ( -) -lepadiformine 8. Two recent syntheses ...
... lipase. Esterification with 5 followed by Ireland-Claisen rearrangement gave 6, that was reduced ... then oxidized to 7. The preparation of the ester 12 began with the commercial ...
... really liked this smart use of a Ireland-Claisen rearrangement to set the stereochemistry about the ... centre in this transformation. The chiral acetate was received from a resolution, and ...
... ketene silyl acetal. On warming, Ireland-Claisen rearrangement of the ketene silyl acetal led ... the acid 8 with remarkable diastereocontrol. The last alkylated stereogenic center of 1 was ...
... ASYMMETRIC HECK REACTION/DIELS-ALDER REACTIONS/IRELAND-CLAISEN REARRANGEMENT/CHIRAL FERROCENYLPHOSPHINE-GOLD(I ) ... /HOMOALLYLIC ALCOHOL DERIVATIVES/ENANTIOSPECIFIC RING EXPANSION/HYDROGEN INSERTION REACTIONS/PROVIDE ADDITIONAL ...
... : 10.1021/acs.orglett.6b01704) by the Ireland-Claisen rearrangement of 33 to 34. The ... protecting group and the use of KHMDS as the base were both critical for maintaining ...
... by Amos Smith, who used an Ireland-Claisen , but is still impressive: Then ... Nelson; an alkene isomerisation and Claisen rearrangement . This approach is very similar to ...
