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Search results for: negishi coupling
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... the carbonyl groups, and allowed a Negishi coupling with an unsaturated partner. RCM ... the medium ring, followed by hydroboration and oxidation of the remaining terminal olefin to ...
... by reducing the azadiene 7 with the Negishi reagent, then adding the nitrile 8 ... intermediate that could be borylated, then coupled under Pd catalysis with an anhydride, ...
... preparation of the silyl ether 5 by Negishi iodomethylation of the butynol 4 followed by ... . Coupling with 6 gave the enyne, that was dihydroxylated under the enantioselective Sharpless ...
... 10.1021/ol2010165) conditions for the Negishi coupling of an alkenyl halide 18 to ... 20 with retention of alkene geometry. Daesung Lee of the University of Illinois, ...
... article for more reactions Abstract Enantioselective decarboxylative Negishi-type alkylations of redox-active esters (RAEs) ... Ni-Catalyzed Enantioselective Dialkyl Carbinol Synthesis via Decarboxylative Cross-Coupling: Development, Scope, and Applications ...
... alcohols , arenes , Fritsch-Buttenberg-Wiechell Rearrangement, Negishi Coupling , Hay Coupling ID: J42-Y2007-4000 ...
... . They then planned to use a Negishi methyliodination to add across the acetylene, ... them to proceed. Performing a Negishi coupling with a TMS-protected acetylene then presented another ...
... examples Key Words Directed Ortho Metalation , Negishi Coupling , Microwave Synthesis ID: J54-Y2008-3150 ... bis-organo zinc species undergo a number of coupling reactions leading to highly functionalized products in ...
... metal chemistry, reducing 9 with stoichiometric Negishi reagent, then coupling the resulting Zr ... with acetyl chloride, leading to 10 as the dominant regioisomer. Hydroboration with subsequent ...
... be used directly in a subsequent Pd-catalyzed Negishi coupling with aryl iodides at 60 C ... see article for more examples Key Words Neghishi Coupling , Zinc , Electrochemistry ID: ...
