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Search results for: nucleophilic substitution
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... 2005, 7, 2973-2975. Palladium-Catalyzed Nucleophilic Benzylic Substitutions of Benzylic Esters R. ... at the Benzylic Position via Palladium-Catalyzed Benzylic Substitution R. Kuwano, Y. Kondo ...
... mmol/mL) and of malonate nucleophile (0.5 mmol/mL) were ... enantioselective iridium-catalyzed allylic alkylation of malonates with trisubstituted allylic electrophiles at ambient temperature provides all-carbon ...
... proceeds smoothly. Allyl silanes are useful nucleophiles for organic synthesis. Terminal vinyl groups ... catalyst that gives preferential epoxidation of the less-substituted alkene. The most general procedure for ...
... so the analogous phenol doesn't have sufficient nucleophilicity to form the ketal. The solution ... (LG) was iodide, cine substitution was preferred over ipso. The solution ...
... /EARLY TRANSITION-METALS/RAY CRYSTAL-STRUCTURE Carbon nucleophile addition to sp(2 ) - ... Key Words: S/SULPHUR Chiral heterosubstituted 1,3-butadienes: Synthesis and [ ...
... 9 could be displaced by an internal nucleophile, to give the product 11 with ... alkyne 17 to make either the less substituted or the more substituted enol phosphate. ...
... with Tf2O and subsequent reaction with weakly nucleophilic nitriles (J . Am. Chem ... that some compounds possessing this spirocyclic-type of substitution exhibit potent anti-ischemic properties without affecting the ...
... , which is not only an oxygen nucleophile but also a nitrogen nucleophile, in ... allylic substitution provides N-(1-allyl)hydroxylamines in good to high yields with ...
... direct coupling reactions between alcohols and silyl nucleophiles in non-halogenated solvents. Highly chemoselective allylations ... 45, 793-796. Key Words allylic substitutions , benzylic substitutions , 1,4-dienes ...
... /ALANYL-D-ALANINE/FORMAL TOTAL SYNTHESIS/NUCLEOPHILIC AROMATIC-SUBSTITUTION/ULLMANN MACROCYCLIZATION REACTION/INHIBITING ... BINDING/INTRAMOLECULAR SNAR REACTION Does CIP nomenclature adequately handle molecules with multiple stereoelements? ...
