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Search results for: nucleophilic substitution
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... 10.1021/acs.joc.9b03041 Abstract A phenyltrimethylammonium tribromide-mediated nucleophilic substitution/oxygen transformation reaction of benzyl ... with DMSO enables a convenient and direct synthesis of various benzyl methyl sulfoxides. In ...
... An intermolecular addition of malononitrile and related pronucleophiles to several 1,3-disubstituted acyclic 1 ... 3-dienes in the presence of a Pd-PHOX catalyst provides products with quaternary stereogenic centers in ...
... enantioselective 1,2-addition reaction using alkenylboron nucleophiles. Addition of various potassium alkenyltrifluoroborates to ... di-, tri-, and tetrasubstituted allylic N-tosyl amines with high asymmetric induction ...
... ketone synthesis with disubstituted (internal) nucleophiles. The method's remarkable tolerance to steric ... including examples of chiral ketone synthesis with disubstituted (internal) nucleophiles. The method's ...
... involves a Vilsmeier-Haack reaction with nonaromatic carbon nucleophiles. The reaction enabled the synthesis of ... more reactions Abstract A preparation of highly substituted ?-amino acids involves a Vilsmeier-Haack reaction with ...
... bromides. The convenient conditions involve a nucleophilic substitution with anions of CH2I2, ICH2Cl ... or CH2Br2 and a subsequent stereoselective base-induced elimination. A facile purification allows rapid access ...
... , sp2-, or sp3-hybridized organometallic C-nucleophiles under mild conditions, and the use ... enables a simple and high-yielding synthesis of 1-substituted cyclopropanols. The transformation is amenable to ...
... ligands to control the regioselectivity of Cu-catalyzed nucleophilic trifluoromethylation reactions of propargyl electrophiles provides various ... -, tri-, and tetrasubstituted (trifluoromethyl)allenes, which can be ...
... a decarboxylative etherification. Alternatively, the nucleophilic substitution of benzyl methyl carbonates with phenols ... in the presence of the catalyst, yielding aryl benzyl ethers. see article for ...
... the carbonyl compound followed by an intramolecular nucleophilic aromatic substitution (SNAr) reaction of ... in situ generated ?,?-unsaturated ketone intermediates. see article for more examples Key ...
