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... 100, 2963. Key Words: NUCLEOPHILIC ACYL SUBSTITUTION/CLOSING OLEFIN METATHESIS/ ... NATURAL-PRODUCTS/INTRAMOLECULAR HECK REACTION/CHROMIUM CARBENE COMPLEXES/LOW-VALENT TITANIUM/NI( ...
URL: https://www.organic-chemistry.org/abstracts/authors/yet-l.shtm
... ligands to control the regioselectivity of Cu-catalyzed nucleophilic trifluoromethylation reactions of propargyl electrophiles provides various ... -, tri-, and tetrasubstituted (trifluoromethyl)allenes, which can be ...
URL: https://www.organic-chemistry.org/abstracts/lit4/950.shtm
... , sp2-, or sp3-hybridized organometallic C-nucleophiles under mild conditions, and the use ... enables a simple and high-yielding synthesis of 1-substituted cyclopropanols. The transformation is amenable to ...
URL: https://www.organic-chemistry.org/abstracts/lit7/493.shtm
... , a surrogate for acetate as a nucleophile was reported (Chem. Commun. ... Zhou at Nankai University. Readily available tri-substituted alkene substrates such as 20 were reduced ...
URL: https://www.organic-chemistry.org/Highlights/2013/18February.shtm
... the 2' azide functionality was introduced by nucleophilic displacement. The displacement and subsequent intramolecular ... Synthesis of Benzoxazoles The synthesis of highly substituted benzoxazoles employing solid-supported reagents was developed by ...
URL: https://www.organic-chemistry.org/Highlights/2008/15July.shtm
... of a nitrile 8 was a powerful nucleophile, smoothly opening an epoxide 10 to ... ) an elegant Wittig-Schlosser approach to geometrically-defined trisubstituted alkenes. Jianbo Wang of Peking University ...
URL: https://www.organic-chemistry.org/Highlights/2011/30May.shtm
... ] revealed that in all cases the nucleophile adds to the same face as the ... a enantioselective catalytic Mukaiyama aldol reaction of methyl-substituted siloxyfuran to derive two stereocenters. A ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn03/azaspiracid-1-evans.shtm
... ) the utility of the enantiomerically-pure allenic nucleophile 19, adding it to the acceptor ... acetonide 21 could be rearranged to the fully-substituted, differentially-protected tetrahydrofuran 22. Paul E ...
URL: https://www.organic-chemistry.org/Highlights/2011/11April.shtm
... 3 catalysis. Via this cycloisomerization/nucleophilic addition sequence, isochromene 2 was obtained ... have disclosed the microwave-assisted three-component reaction of 3-substituted 5-aminopyrazoles 1, pyruvic acid or ethyl ...
URL: https://www.organic-chemistry.org/Highlights/2007/15February.shtm
... amide, allowing efficient coupling with organometallic nucleophiles to form the corresponding ketones. Another ... examples given were also ?-aryl or ?-heteroaryl substituted. It will be interesting to learn ...
URL: https://www.organic-chemistry.org/Highlights/2006/29May.shtm
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