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Search results for: nucleophilic substitution
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... tolerates various functional groups on both the nucleophilic and electrophilic partner. Reactions of highly ... E- and Z-alkenyltrifluoroborates, as well as vinyl- and propenyltrifluoroborates, were successful ...
... the authors took advantage of the marked nucleophilicity of allyl magnesium bromide (and chloride ... second alkyne led to 8. The trisubstituted alkene of 10 was set by conjugate ...
... work. In a variation on vicarious nucleophilic substitution, Mieczyslaw Makosza of the Polish ... of Sciences demonstrated (Chem. Commun. 2016, 52, 12650. DOI ...
... different heterocycles by substituting thiourea with other nucleophiles. The study highlights the importance of ... allowing the synthesis of different heterocycles by substituting thiourea with other nucleophiles. The study ...
... 1994, 575. Key Words: Nucleophilic aromatic substitution - A possible key step ... total syntheses of vancomycin. K. Burgess, D. Lim, C. ...
... reagent that readily reacts with an amine nucleophile. This oxidative N-cyanation reaction enables the ... of disubstituted cyanamides without using highly toxic cyanogen halides. see article for more examples ...
... , 379. Key Words: Cr Nucleophilic Additions to Organotransition Metal Cations Containing Unsaturated ... Cr Stereoselective manipulation of acetals derived from o-substituted benzaldehyde chromium tricarbonyl compleses. S. ...
... generated triazolium enolate intermediates serve as two-carbon nucleophiles that undergo highly enantioselective reactions with enones ... ?,?-unsaturated imines to give ?-unsubstituted ?-lactones and lactams, respectively. see article ...
... as it addresses the previously challenging catalytic nucleophilic substitution at C(sp3)Cl ... , which often suffer from ?-hydride elimination. The study highlights the use of various ...
... radical addition, single-electron oxidation, and nucleophilic attachment, leading to the formation of ... Stereoselective Cyclopropanation of Multisubstituted Enesulfinamides: Asymmetric Construction of ?-Tertiary Cyclopropylamine Derivatives Containing ?-Quaternary ...