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... , the Brown reagent 8 delivered the desired Felkin product 9. Protection followed by ozonolysis gave the aldehyde 10. Crotylation with the Roush-developed tartrate 11 then gave the ...
URL: https://www.organic-chemistry.org/Highlights/2008/03November.shtm
... :5 regioselectivity, and in up to 96% ee. In conjunction with ozonolysis, this process allows the enantioselective synthesis of ?-hydroxy ketones. see article for ...
URL: https://www.organic-chemistry.org/abstracts/literature/112.shtm
... nice it is! This frament was quickly converted to a THF using an efficient ozonolysis of a methylene to free the ketone and cyclise in acid to the THF ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn03/azaspiracid-1-evans.shtm
... of ester 1 began with geranic acid (4 ) . Alkylative esterification followed by ozonolysis led to 5, that was coupled with 6 to give 7. Usually ...
URL: https://www.organic-chemistry.org/Highlights/2019/04November.shtm
... DOI: 10.1055/s-0030-1260244) that Na triacetoxyborohydride reduced the methoxy hydroperoxide from the ozonolysis of 3 to the aldehyde 4. Reductive amination of 4 can be effected ...
URL: https://www.organic-chemistry.org/Highlights/2012/10September.shtm
... . DOI: 10.1021/acs.orglett.5b00637) the selenide 1 to the alkene 2 under ozonolysis conditions. Takamitsu Hosoya of the Tokyo Medical and Dental University found (Chem ...
URL: https://www.organic-chemistry.org/Highlights/2015/26October.shtm
... tricyclic 2. The starting material for the synthesis was the inexpensive dihydrocarvone 4. Ozonolysis and oxidative fragmentation following the White protocol delivered 5 in high ee. Conjugate ...
URL: https://www.organic-chemistry.org/Highlights/2013/04November.shtm
... via methyl ketone formation, Baeyer-Villiger oxidation and dehydration, to the alkene 11. Ozonolysis followed by ?-elimination delivered the enone 12, that was oxidized by a cytochrome ...
URL: https://www.organic-chemistry.org/Highlights/2023/04September.shtm
... each in enantiomerically-pure form. The preparation of 7 began with commercial citronellol 4. Ozonolysis followed by Wittig reaction with the phosphorane 5 and oxidation delivered 6, that ...
URL: https://www.organic-chemistry.org/Highlights/2016/01February.shtm
... - a Sharpless dihydroxylation , followed by addition of periodate. Presumably the more direct ozonolysis was unselective, and attacked the freshly installed vinyl iodide. The tetrahydropyran-containing unit ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn05/sorangicin-a-smith.shtm
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