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Search results for: pinacol rearrangement
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... 28 to the ketone 27 followed by pinacol rearrangement . Zhaoguo Zhang of Shanghai Jiao ... University and Tahar Ayad and Virginie Ratovelomanana-Vidal of Chimie ParisTech coupled (ACS Catal. ...
... Lausanne used a phosphoramide to mediate the pinacol rearrangement of 19 to 20 (J ... Am. Chem. Soc. 2019, 141, 11372. DOI: 10.1021 ...
... 8 followed by protection and Lewis acid-mediated pinacol rearrangement to give 9. The corresponding ... 10 was cyclized to the ketone 11. Following the House precedent established decades ago ...
... pincer complex catalyzes the anti-Markovnikov addition of pinacolborane to terminal alkynes yielding Z-vinylboronates at mild ... . The catalytic cycle involves rearrangement of coordinated alkyne to Z-vinylidene as a key step ...
... ) a tandem Nazarov /semi- pinacol rearrangement that transformed 29 into 30. ... Dixon and Ye conceived (Angew. Chem. Int. Ed. 2015, ...
... . Despite encouraging literature reports, the pinacol cyclization of 1 with SmI2 was not ... dehydration of the diol led predominantly to rearrangement, so the more exposed tertiary alcohol ...
... the central feature of which was the Prins-pinacol combination of 1 with 2 to give ... 2 to give, via Lewis acid-mediated rearrangement of the initially-prepared acetal, the aldehyde ...
... by way of addition followed by a pinacol-type rearrangement, to give the amide 12 ... The regioselectivity of the bond migration is remarkable. Reduction of the amide then gave ...
... /MCMURRY REACTIONS/TITANIUM COMPOUNDS/PINACOL COUPLING REACTION/KETO ESTER CYCLIZATION/ ... TOTAL SYNTHESIS/CHROMIUM-REFORMATSKY REACTION/SILYLOXY-COPE REARRANGEMENT/EFFICIENT TOTAL SYNTHESIS/LOW-VALENT TITANIUM ...
