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... products to the Z-alkene was straightforward. Reduction of the isolated alkyne to the E-alkene ... general solution to the long-standing challenge of E-reduction of an alkyne in the presence of ...
... C7CC01561E) an organocatalyst to mediate the reduction of 19 to 20. Matthew J ... /anie.201610990) the selective 1,2-reduction of the enone 3 to the allylic ...
... hydrogen surrogate enables a ligand-free Co-catalyzed chemoselective reductive cyclization cascade of enone-tethered aldehydes. The ... between Michael-Aldol cycloreduction cascade and oxa-Michael cascade can be adjusted by the addition of TEMPO ...
... a group of versatile and powerful polymer-supported reductants. A. Kirschning, J. ... 6-DIDEOXYHEXOSES/HIGHLY STEREOSELECTIVE SYNTHESIS/GLUCOSE-FRUCTOSE OXIDOREDUCTASE/ANGUCYCLINE GROUP ANTIBIOTICS/NUCLEAR-MAGNETIC-RESONANCE/ ...
... C-15 silanol. Thus, a distereoselective reduction of the C-15 ketone with CBS catalyst ... upon the open-chain aldehyde analogue (requiring reduction-protection-oxidation) . They then set about a ...
... the imide would be easily distinguishable by reduction of the aldehyde followed by selective formation ... ) that crude purified p51 and p83 reductases from Glycine max showed showed complementary selectivity ...
... see article for more examples Key Words reduction of alkenes , 1,4-reduction of ... ,?-unsaturated compounds , 1,4-dioxane ID: J54-Y2019 ...
... . Key Words: FUNCTIONAL GROUPS/REDUCTION/Si/HYDROMETALLATION T. Hiyama ... Chemistry Portal Novel synthetic strategy for HMG-CoA reductase inhibitors. T. Hiyama, Pure ...
... enantio- and chemoselective copper hydride catalyzed semireduction of conjugated enynes provides 1,3-disubstituted ... for more examples proposed mechanism Key Words semi-reduction of 1,3-enynes , silanes , ...
... was not reported. Both hydrogenation ( Rosenmund ) and hydride have been used to ... ether 7 to the sulfonamide 8. Reduction then delivered the hydroxy sulfonamide 9. ...
