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Search results for: sharpless dihydroxylation
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... Construction of Arrays of Stereogenic Centers The Sharpless osmium-catalyzed asymmetric dihydroxylation is widely used. ... Que, Jr. of the University of Minnesota designed (Angew. Chem. ...
... that cyclization of 8, prepared by Sharpless asymmetric epoxidation followed by Sharpless asymmetric dihydroxylation ... also proceeded with high diastereocontrol. Vincent Aucagne of the Université d'Orléans observed (Tetrahedron ...
... /MULTIPLICATION/HOMOCHIRALITY Polymer-supported catalytic asymmetric Sharpless dihydroxylations of olefins. C. Bolm ... A. Gerlach, Eur. J. Org. Chem., 1998, ...
... from the simple precursor 30 by sequential Sharpless asymmetric epoxidation and Sharpless asymmetric dihydroxylation ( ... . Org. Chem. 2021, 86, 4859. DOI: 10.1021/ ...
... . Bolm, K. B. Sharpless, Angew. Chem., Int ... Words: ASYMMETRIC SYNTHESES/CATALYSIS/DIHYDROXYLATIONS/EPOXIDATIONS/TITANIUM COMPOUNDS/CHIRAL ...
... jo048863o) used the power of the Sharpless oxidations ( epoxidation , dihydroxylation ) to ... the prochiral 10 into the epoxy diol 11. Base-catalyzed cascade cyclization then converted 11 ...
... using the usual reagents failed, but Sharpless asymmetric dihydroxylation was successful, providing the ... in > 96:4 diastereoselectivity, with only traces of the tetraol and of ...
... to terminal olefins from prim-alcohols (the Grieco-Sharpless olefination reaction) and to the regioselective ... 515. Key Words: Se Asymmetric dihydroxylation of C,C double bonds using ...
... epoxidation and dihydroxylation , developed by Barry Sharpless have dominated single-enantiomer organic synthesis. Recently ... The enantioselective oxygenation procedures, epoxidation and dihydroxylation , developed by Barry Sharpless have dominated ...
... can be prepared in high ee by Sharpless dihydroxylation, it would be even more ... to prepare them by direct asymmetric pinacol coupling. N. N. Joshi of ...
