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Search results for: sharpless dihydroxylation
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... coupling with 5 led to 6. Sharpless asymmetric dihydroxylation followed by protection delivered 8 ... 96% ee. The ?-alkoxy radical derived from the telluride 9 was added in ...
... four steps, commencing with an asymmetric Sharpless dihydroxylation , followed by carbonate formation and ... catalysed reduction, and finally diastereoselective hydration with benzaldehyde to generate the 3,5-benzylidene ...
... ) that this acceleration also worked with Sharpless asymmetric dihydroxylation . D. Christopher Braddock ... Imperial College London took advantage (Chem. Commun. 2014, 50, 13725 ...
... , that was dihydroxylated under the enantioselective Sharpless conditions , leading to the diol 7 ... 6 gave the enyne, that was dihydroxylated under the enantioselective Sharpless conditions , leading ...
... they used a two-step protocol - a Sharpless dihydroxylation , followed by addition of periodate ... Presumably the more direct ozonolysis was unselective, and attacked the freshly installed vinyl iodide ...
... paper describes the use of a double Sharpless asymmetric dihydroxylation sequence, in which the ... alkene reacts first, forming the tetrahydrofuran, and then the terminal alkene to form ...
... " epoxide isn't actually made from a Sharpless epoxidation ; they actually do a dihydroxylation ... and then selectively mesylate and displace to leave the desired epoxide. With the epoxides ...
... initiated their synthesis of 10 with the Sharpless asymmetric dihydroxylation of the unsaturated ester 8 ... leading to the lactone 9 (Synlett 2022, 34, 271) . Fernando ...
... from the aldehyde 10, prepared by Sharpless asymmetric dihydroxylation of 3-pentenenitrile. Chelate-controlled addition ... propargyl zinc 11 led to the alkyne 12. Reductive coupling of the alkyne of ...
... set the absolute configuration of 15 by Sharpless asymmetric dihydroxylation , then cyclized it to ... with a Rh catalyst (Chem. Sci. 2019, 10, 535. ...