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... , the group managed this using a Sharpless dihydroxylation , using the conformation of the ... rings to control this. Only the less hindered, equatorial vinyl group reacts in ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn02/phorboxazole-b-burke.shtm
... in Strasbourg prepared the substrate 20 for Sharpless asymmetric epoxidation using the method that we ... 10 led to 12, which after dihydroxylation and protection was heated to generate the ...
URL: https://www.organic-chemistry.org/Highlights/2007/22January.shtm
... with the absolute configuration being set by Sharpless asymmetric epoxidation . Subsequent to the alkylation ... but not ?) could effect selective dihydroxylation. Periodate cleavage followed by reduction then ...
URL: https://www.organic-chemistry.org/Highlights/2007/05November.shtm
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