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... . For more than two decades, Sharpless asymmetric epoxidation of allylic alcohols has been ... workhorse for enantioselective synthesis. Karl Anker Jørgensen of Aarhus University, Denmark, has ...
URL: https://www.organic-chemistry.org/Highlights/2006/13February.shtm
... relative and absolute configuration of 33 by Sharpless asymmetric epoxidation of the allylic alcohol 30 ... conversion of the alcohol 9 to the epoxide 10 (Angew. Chem. Int ...
URL: https://www.organic-chemistry.org/Highlights/2022/25July.shtm
... easily; asymmetry was introduced via a Sharpless epoxidation , and the resulting epoxide opened ... an allyl cuprate. A few more steps including a 1-c homologation returned the desired ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn05/polyanthellin-a-johnson.shtm
... epoxidation and dihydroxylation , developed by Barry Sharpless have dominated single-enantiomer organic synthesis. Recently ... Carbonyl Compounds The enantioselective oxygenation procedures, epoxidation and dihydroxylation , developed by Barry Sharpless ...
URL: https://www.organic-chemistry.org/Highlights/2005/28February.shtm
... Enantioselective Construction of Arrays of Stereogenic Centers Sharpless asymmetric epoxidation has long been a workhorse ... enantioselective synthesis. The SAE protocol, however, gives only mediocre ee's with cis ...
URL: https://www.organic-chemistry.org/Highlights/2006/31July.shtm
... DOI: 10.1021/jo301145r) the Sharpless-derived epoxide 6 to the cyclopentane nitrile 7 ... Daesung Lee of the University of Illinois at Chicago generated (Org. Lett. ...
URL: https://www.organic-chemistry.org/Highlights/2013/30December.shtm
... III) reduction of epoxides to the Sharpless-derived ether 6, leading to the pyrrolidine ... the Ti(III) reduction of epoxides to the Sharpless-derived ether 6, leading ...
URL: https://www.organic-chemistry.org/Highlights/2009/23November.shtm
... /SYNTHESIS/TM CATALYSTS/REDUCTION SHARPLESS EPOXIDATION CYCLOPROPANATION DIELS-ALDER ALDOL HYDROGENATION CROSS COUPLING ... /HETRING/3 (O )/ TM Enantioselective Synthesis of Organic Compounds with ...
URL: https://www.organic-chemistry.org/abstracts/authors/brunner-h.shtm
... /anie.201003236) the conversion of the Sharpless-derived epoxide 1 into the cyclopropane 2. ... D. Bray of Queen Mary University of London established (Chem. Commun. ...
URL: https://www.organic-chemistry.org/Highlights/2011/22August.shtm
... the epoxide 6, prepared by the Sharpless procedure , undergoes just such an opening ... : 10.1039/b709627e) that the epoxide 6, prepared by the Sharpless procedure ...
URL: https://www.organic-chemistry.org/Highlights/2008/21April.shtm
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