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Search results for: stille coupling

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... and oxidation followed by condensation with the Still-Gennari phosphonate completed the assembly of 1. ... dehydration to the cyclopentene followed by reductive coupling with lithium dimethylcuprate and iodination gave the ...
URL: https://www.organic-chemistry.org/Highlights/2022/03January.shtm
... acid, but the key step is still the carbene chemistry. Using p-ABSA to ... , they used a pretty neat Heck-style coupling developed by Cook. Hoping to do ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn05/vincorine-qin.shtm
... , the first interesting applications of this still young reaction in the synthesis of natural ... ascribed to their widespread utility in Suzuki-Miyaura coupling . Several hundred alkyl, aryl and ...
URL: https://www.organic-chemistry.org/Highlights/2005/05June.shtm
... m-hydroxy-phenol delivering the electrophilic component for a Stille reaction . Coupling to an allyl silane ... and elimination of a mesyl group then finished the cyclisation substrate, which was treated ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn02/11-o-debenzoyltashironin-danishefsky.shtm
... With 2 in hand, there was still the challenge of assembling the seven-membered ring ... methylation of 8, followed by Pd-mediated coupling of the alkenyl organometallic so generated with ...
URL: https://www.organic-chemistry.org/Highlights/2010/01February.shtm
... fairly impressive yield. However, they still had one more epoxide to make, ... from here was a matter of a couple of steps, and completed a rather ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn02/intricatetraol-morimoto.shtm
... cyclization no doubt intially left the alkene still conjugated with the ester, but traces ... diazo transfer gave 11, which was coupled with 8 to give 1. The ...
URL: https://www.organic-chemistry.org/Highlights/2007/02July.shtm
... natural product anymore, the compound is still a neat, compact target! Key ... constructed the carbon skeleton in only a couple of steps, but the reaction couldn't ...
URL: https://www.organic-chemistry.org/totalsynthesis/totsyn05/7-methylomuralide-corey.shtm
... homologation then gave the precursor 15 for Stille coupling to close the last ring. ... of the hemiaminal, oxidation with bicarbonate-buffered Dess-Martin reagent to the aldehyde (zwitterionic! ...
URL: https://www.organic-chemistry.org/Highlights/2007/04June.shtm
... Delaware Stereocontrolled C-O Ring Construction Sugars are still useful chiral pool starting materials for the ... ?-galactosyl iodide work, showing that 1 couples with vinyl magnesium bromide to give 2 ...
URL: https://www.organic-chemistry.org/Highlights/2007/09April.shtm
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