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Synthesis of alkynylboronic acids and alkynylboronates

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ZnBr2 is a highly efficient and chemoselective catalyst for the dehydrogenative borylation of terminal alkynes with HBpin under mild conditions. The reaction shows a good tolerance toward various functional groups.
M. Luo, Y. Qin, X. Chen, Q. Xiao, B. Zhao, W. Yao, M. Ma, J. Org. Chem., 2021, 86, 16666-16674.