Categories: C-C Bond Formation >

Arenes

Alkylation
(and reactions not
mentioned below)

Versatile Cross Coupling Methods:

Hiyama Coupling
(R-X + R'-SiR''₃)

Hiyama-Denmark Coupling
(R-X + R-SiMe₂OH)

Kumada Coupling
(R-X + R'-MgX)

Negishi Coupling
(R-X + R'-ZnX)

Stille Coupling
(R-X + R'-SnR''₃)

Suzuki Coupling
(R-X + R'-BY₃)

Cyclization

Alkenylation

Biaryl Synthesis

Alkynylation

Synthesis of Diarylmethanes,
Benzylation

Allylic substitution Propargylation

α-Arylation 1,4-Addition

Synthesis of alcohols Synthesis of amines

Acylation Formylation

Carboxylation,
Synthesis of benzamides
and related compounds Sandmeyer Reaction,
Cyanation

Alkylation (and reactions not mentioned below)		Versatile Cross Coupling Methods: Hiyama Coupling (R-X + R'-SiR''₃) Hiyama-Denmark Coupling (R-X + R-SiMe₂OH) Kumada Coupling (R-X + R'-MgX) Negishi Coupling (R-X + R'-ZnX) Stille Coupling (R-X + R'-SnR''₃) Suzuki Coupling (R-X + R'-BY₃)
Cyclization
Alkenylation
Biaryl Synthesis
Alkynylation
Synthesis of Diarylmethanes, Benzylation
Allylic substitution	Propargylation
α-Arylation	1,4-Addition
Synthesis of alcohols	Synthesis of amines
Acylation	Formylation
Carboxylation, Synthesis of benzamides and related compounds	Sandmeyer Reaction, Cyanation