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Synthesis of substituted carbonyl compounds by 1,6-Additions


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The catalytic iridium-catalyzed 1,6-addition of aryl boronic acids to electron-deficient dienes gave high yields of the corresponding δ-arylated carbonyl compounds with perfect 1,6-selectivity.
T. Nishimura, Y. Yasuhara, T. Hayashi, Angew. Chem. Int. Ed., 2006, 45, 5164-5166.