Categories: C-C Bond Formation > Nitrogen-containing molecules >
Synthesis of β-Aminonitriles
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Recent Literature
Cooperative catalysis of a cationic Ru complex, DBU, and NaPF6 enabled
activation of acetonitrile as a nucleophile under mild basic conditions. The
nucleophilic 1,2-addition of in situ-generated, Ru-bound, metalated nitrile to
aldehydes and imines proceeded smoothly.
N. Kumagai, S. Matsunaga, M. Shibasaki, J. Am. Chem. Soc.,
2004,
126, 13632-13633.