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Synthesis of Sulfide Derivatives

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A half-sandwich scandium complex catalyzes a regioselective α-C(sp3)-H addition of a wide range of methyl sulfides to a variety of olefins and dienes in a 100% atom efficient fashion to provide diverse sulfide derivatives.
Y. Luo, Y. Ma, Z. Hou, J. Am. Chem. Soc., 2018, 140, 114-117.