Categories: C-F Bond Formation >
Synthesis of trifluoromethylated compounds
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CF3-cyclopropanes with aliphatic, aromatic, and even heteroaromatic
substituents were prepared on a multigram scale by deoxyfluorination of
cyclopropane carboxylic acids or their potassium salts (in case of labile
α-pyridine acetic acids) with sulfur tetrafluoride.