Categories: C-N Bond Formation >
Synthesis of sulfamides
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Recent Literature
The combination of [Ir(ppy)2(dtbbpy)]PF6 as a
photosensitizer, NiBr2·glyme as a precatalyst, and
1,8-diazabicyclo(5.4.0)undec-7-ene (DBU) as a base enables an N-arylation
of sulfamides with aryl bromides at room temperature under visible light
irradiation. The reaction tolerates aryl boronic esters and aryl chlorides.
R. T. Simons, G. E. Scott, A. G. Kanegusuki, J. L. Roizen, J. Org. Chem., 2020, 85,
6380-6391.