Categories: C-O Bond Formation >
Synthesis of carbonates and related compounds
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Recent Literature
Bench stable N-Methyl-O-alkoxyformate hydroxylamine
hydrochloride reagents can be prepared in two high-yielding steps from N-Boc-N-methyl
hydroxylamine. Subsequent reaction with various carbonyl compounds give the
corresponding α-functionalised products in good yield via a proposed
[3,3]-sigmatropic rearrangement.
A. Hall, K. L. Jones, T. C. Jones, N. M. Killeen, R. Pörzig, P. H. Taylor, S.
C. Yau, N. C. O. Tomkinson, Synlett, 2006,
3435-3438.