Categories: C-O Bond Formation >
Synthesis of esters
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Recent Literature
An effective method for the construction of esters from acyl chloride and
halohydrocarbon using Cs2CO3 as an oxygen source has a
wide scope of substrates and can be scaled up. This esterification proceeds
through a free radical reaction. CO2 can also be used as an oxygen
source.
L. Ren, L. Wang, Y. Lv, G. Li, S. Gao, Org. Lett.,
2015,
17, 5172-5175.
The synthesis of a planar-chiral bisflavin catalyst (1) and its use
in asymmetric Bayer-Villiger-Oxidations is described.
S. Murahashi, S. Ono, Y. Imada, Angewandte Chemie, 2002,
114, 2472.
The chemoselective ring opening of N-tosyl aziridines with aldehydes
catalyzed by an N-heterocyclic carbene gave carboxylates of 1,2-amino alcohols. A plausible mechanism for this reaction
is discussed.
Y.-K. Liu, R. Li, L. Yue, B.-J. Li, Y.-C. Chen, Y. Wu, L.-S. Ding, Org. Lett.,
2006,
8, 1521-1524.