Categories: C-P Bond Formation >
Synthesis of thiophosphines
Recent Literature
A palladium-catalyzed deformylative P-C cross-coupling reactions of
hydroxymethylphosphine derivatives enables a practical and versatile syntheses
of tertiary phosphine derivatives. Sequential couplings of orthogonally
protected precursors provide a simple and practical route toward a variety of
tertiary aryl-substituted phosphine derivatives in any combination.
M. Hayashi, T. Matsuura, I. Tanaka, H. Ohta, Y. Watanabe, Org. Lett., 2013,
15, 628-631.
A catalytic amount of a Brønsted base mediates a stereoselective
diphosphination of terminal alkynes with diphosphanes to deliver the
corresponding (E)-1,2-diphosphinoethenes in good yields. This
reaction offers a good alternative to precedented transition-metal-catalyzed
or radical-promoted approaches to the 1,2-diphosphinoethene framework of
potent interest in catalysis and coordination chemistry.
Y. Okugawa, K. Hirano, M. Miura, Org. Lett., 2017, 19, 2973-2976.
A stereoselective hydrophosphination reaction of alkynes with diphenylphosphane has been developed. The reaction is mediated by a cobalt catalyst and butyllithium.
H. Ohmiya, H. Yorimitsu, K. Oshima, Angew. Chem.
Int. Ed., 2005,
44, 2368-2370.