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Synthesis of imino sulfides (thioimidates)


Recent Literature

A N-trifluoromethylation of nitriles with PhICF3Cl followed by DMAP-catalyzed capture with N-, O-, or S-centered nucleophiles enables an efficient synthesis of a wide range of N-CF3 amidines, imidates, and thioimidates.
R. Z. Zhang, W. Huang, R. X. Zhang, C. Xu, M. Wang, J. Sun, Org. Lett., 2022, 24, 2393-2398.