Categories: C-S Bond Formation >
Synthesis of imino sulfides (thioimidates)
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Recent Literature
A N-trifluoromethylation of nitriles with PhICF3Cl
followed by DMAP-catalyzed capture with N-, O-, or S-centered nucleophiles enables an efficient
synthesis of a wide range of N-CF3 amidines, imidates, and
thioimidates.
R. Z. Zhang, W. Huang, R. X. Zhang, C. Xu, M. Wang, J. Sun, Org. Lett.,
2022, 24, 2393-2398.