Synthesis of sulfilimines

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The reaction of sulfinimidate esters with Grignard reagents enables the preparation of protected sulfilimines in high yields and with a remarkable structural variability. Moreover, the transformation can be performed in cyclopentyl methyl ether as a green solvent.
M. Andresini, M. Spennachio, M. Colella, G. Losito, A. Aramini, L. Degennaro, R. Luisi, Org. Lett., 2021, 23, 6795-6800.