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Synthesis of ketones by hydrolysis of enol ethers
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An enantioselective protonation reaction of silyl enol ethers of ketones in the
presence of a cationic gold(I) disphosphine complex as chiral Brønsted acid and
of alcoholic solvent gave optically active cyclic and acyclic ketones in
excellent yields and high enantioselectivities.
C. H. Cheon, O. Kanno, F. D. Toste, J. Am. Chem. Soc., 2011,
133, 12875-12879.