N-Si Bond Formation

Recent Literature

A catalytic dehydrogenative coupling of dihydrosilanes with anilines enables a highly enantioselective synthesis of silicon-stereogenic silazanes in excellent yields and stereoselectivities. In addition,  straightforward transformations of the enantioenriched silazanes deliver various chiral silane compounds in a stereospecific fashion.
M.-M. Liu, Y. Xu, C. He, J. Am. Chem. Soc., 2023, 145, 11727-11734.