Categories: N-O Bond Formation >
Synthesis of O-nitroso compounds
A N-nitrososulfonamide can be used as chemical reagent for transnitrosation under mild experimental conditions. This reagent is stable to air and moisture across a broad range of temperatures and offers high functional group tolerance for substrates that are susceptible to oxidation or reversible transnitrosation. The sulfonamide byproduct is easily recovered to regenerate the reagent.
J. D. Galloway, C. Sarabia, J. C. Fettinger, H. P. Hratchian, R. D. Baxter, Org. Lett., 2021, 23, 3253-3258.