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Synthesis of Sulfinamidines

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N-Bromosuccinimide mediates a tandem oxidative/nucleophilic substitution approach for the synthesis of sulfinamidines from readily availables sulfenamides and amines in high yield without any additives or catalysts. This method is highly time-economical, safe to operate, and easy to scale up and offers excellent functional group compatibility.
G.-f. Yang, H.-s. Huang, X.-k. Nie, S.-q. Zhang, X. Cui, Z. Tang, G.-x. Li, J. Org. Chem., 2023, 88, 4581-4591.