Categories: S-O Bond Formation >
Synthesis of fluorosulfates
Recent Literature
Rapid ex situ generation of gaseous sulfuryl fluoride (SO2F2)
from 1,1′-sulfonyldiimidazole as a precursor enables a convenient transformation
of phenols into the corresponding aryl fluorosulfates using a two-chamber
reactor. Various phenols and hydroxylated heteroarenes were fluorosulfated in
good to excellent yields.
C. Veryser, J. Demaerel, V. Bieliu̅nas, P. Gilles, W. M. De Borggraeve, Org. Lett.,
2017, 19, 5244-5247.