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Synthesis of sulfinimidate esters

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Phenyliodonium diacetate mediates an efficient oxidative esterification of sulfenamides to provide sulfinimidate esters and sulfilimines under mild and metal-free conditions in very good yields. The protocol is readily scalable and compatible with a diverse range of substrates and functional groups.
X. Lu, G. Huang, J. Ye, M. A. Bashir, J. Su, K. Yang, F. Liang, X. Xu, Org. Lett., 2023, 25, 2151-2156.