Categories: O-Si Bond Formation >
Synthesis of silanols
Recent Literature
Adsorbed [RuCl2(p-cymene)]2
on activated carbon is an efficient, environmentally attractive and highly
selective catalyst for use in aerobic oxidations, hydrolytic oxidations and
dehydrations. The heterogeneous catalyst was recovered quantitatively by simple
filtration and could be reused with minimal loss of activity.
E. Choi, C. Lee, Y. Na, S. Chang, Org. Lett., 2002, 4,
2369-2371.
[IrCl(C8H12)]2 catalyzed the hydrolytic
oxidation of organosilanes to the corresponding silanols under essentially
neutral and mild conditions with high efficiency. Various types of silanols
are produced in good to excellent yields.
Y. Lee, D. Seomoon, S. Kim, H. Han, S. Chang, P. H. Lee, J. Org. Chem.,
2004, 69, 209-212.
