Categories: O-Si Bond Formation >
Synthesis of silanols
Adsorbed [RuCl2(p-cymene)]2 on activated carbon is an efficient, environmentally attractive and highly selective catalyst for use in aerobic oxidations, hydrolytic oxidations and dehydrations. The heterogeneous catalyst was recovered quantitatively by simple filtration and could be reused with minimal loss of activity.
E. Choi, C. Lee, Y. Na, S. Chang, Org. Lett., 2002, 4, 2369-2371.
[IrCl(C8H12)]2 catalyzed the hydrolytic oxidation of organosilanes to the corresponding silanols under essentially neutral and mild conditions with high efficiency. Various types of silanols are produced in good to excellent yields.
Y. Lee, D. Seomoon, S. Kim, H. Han, S. Chang, P. H. Lee, J. Org. Chem., 2004, 69, 209-212.